Redox Non‐Innocence of Nitrosobenzene at Nickel
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چکیده
منابع مشابه
Octahedral to trigonal prismatic distortion driven by subjacent orbital π antibonding interactions and modulated by ligand redox noninnocence.
Ru(ONO)2 and Os(ONO)2 distort from octahedral towards trigonal prismatic geometry in order to relieve π antibonding due to donation from the second-highest ligand orbital to the metal. Increasing oxidation of the ONO ligand suppresses distortion by increasing σ* interactions in the trigonal prism.
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2016
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.201605026